Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]
نویسندگان
چکیده
منابع مشابه
Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]
In the structure of the title complex, [Cs(C7H4NO2)(H2O)2] n , the caesium salt of 4-nitro-benzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxyl-ate O,O'-chelate inter-action, a triple-bridging water mol-ecule and a monodentate water mol-ecule. A three-dimensional framework polymer is generated, within which there are water-carbo...
متن کاملPoly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium]
In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)] n , the caesium salt of the commercial herbicide fenac [(2,3,6-tri-chloro-phen-yl)acetic acid], the irregular eight-coordination about Cs(+) comprises a bidentate O:Cl-chelate inter-action involving a carboxyl-ate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxyl-ate-O atom and a b...
متن کاملPoly[μ2-aqua-aqua-μ5-naphthalene-2,7-disulfonato-strontium]
In the crystal structure of the polymeric title compound, [Sr(C(10)H(6)O(6)S(2))(H(2)O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO(3) unit to bind to two Sr(II) cations and the other -SO(3) unit to bind to three Sr(II) cations; of the two coordinated water mol-ecules, one is monodentate to one Sr(II) cation, whereas the other bridges two Sr(II) cations. The μ(5)-bridging mode ...
متن کاملPoly[μ3-aqua-aqua(μ3-3,5-dinitrobenzoato-κO 1:O 3:O 5)caesium]
In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitro-benzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water mol-ecules (one triply bridging and the other monodentate) and four O-atom donors from two nitro groups and one bridging carboxyl-ate O-atom donor from the ligand. Intra-unit O-H⋯O hydrogen-bo...
متن کاملPoly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium]
In the title compound, [K2(C7H3Cl2O2)2(H2O)] n , the potassium salt of 2,4-di-chloro-benzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO6Cl units related by twofold rotational symmetry, linked by a bridging water mol-ecule lying on the twofold axis. The coordination polyhedron about the K(+) ion comprises a carboxyl-ate O atom and a Cl-atom donor f...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2013
ISSN: 1600-5368
DOI: 10.1107/s1600536813030638